- Title Page
- Copyright Page
- Dedication Page
- Contents
- Preface
- Acknowledgments
- About the Author
- Nomenclature
- Part I. Pure Fluids
- Chapter 1. Scope and Language of Thermodynamics
- Chapter 2. Phase Diagrams of Pure Fluids
- 2.1 The PVT Behavior of Pure Fluid
- 2.2 Tabulation of Properties
- 2.3 Compressibility Factor and the ZP Graph
- 2.4 Corresponding States
- 2.5 Virial Equation
- 2.6 Cubic Equations of State
- 2.7 PVT Behavior of Cubic Equations of State
- 2.8 Working with Cubic Equations
- 2.9 Other Equations of State
- 2.10 Thermal Expansion and Isothermal Compression
- 2.11 Empirical Equations for Density
- 2.12 Summary
- 2.13 Problems
- Chapter 3. Energy and the First Law
- Chapter 4. Entropy and the Second Law
- 4.1 The Second Law in a Closed System
- 4.2 Calculation of Entropy
- 4.3 Energy Balances Using Entropy
- 4.4 Entropy Generation
- 4.5 Carnot Cycle
- 4.6 Alternative Statements of the Second Law
- 4.7 Ideal and Lost Work
- 4.8 Ambient Surroundings as a Default Bath—Exergy
- 4.9 Equilibrium and Stability
- 4.10 Molecular View of Entropy
- 4.11 Summary
- 4.12 Problems
- Chapter 5. Calculation of Properties
- 5.1 Calculus of Thermodynamics
- 5.2 Integration of Differentials
- 5.3 Fundamental Relationships
- 5.4 Equations for Enthalpy and Entropy
- 5.5 Ideal-Gas State
- 5.6 Incompressible Phases
- 5.7 Residual Properties
- 5.8 Pressure-Explicit Relations
- 5.9 Application to Cubic Equations
- 5.10 Generalized Correlations
- 5.11 Reference States
- 5.12 Thermodynamic Charts
- 5.13 Summary
- 5.14 Problems
- Chapter 6. Balances in Open Systems
- Chapter 7. VLE of Pure Fluid
- Part II. Mixtures
- Bibliography
- Appendix A. Critical Properties of Selected Compounds
- Appendix B. Ideal-Gas Heat Capacities
- Appendix C. Standard Enthalpy and Gibbs Free Energy of Reaction
- Appendix D. UNIFAC Tables
- Appendix E. Steam Tables
- Index
- Add Pages
Appendix D. UNIFAC Tables
Table D-1: Parameters for the UNIFAC Equation. “Main” refers to the index of the main group; k refers to the index of the subgroup.
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